1H-Imidazo[4,5-f][1,10]phenanthrolin-7-ium perchlorate monohydrate
نویسنده
چکیده
In the title crystal structure, C(13)H(9)N(4) (+)·ClO(4) (-)·H(2)O, cations, anions and water mol-ecules are linked through inter-molecular N-H⋯O, O-H⋯N and O-H⋯O hydrogen bonds, forming layers parallel to (001). In addition, there are weak π-π stacking inter-actions between the layers, involving the cations and with centroid-centroid distances in the range 3.584 (2)-3.662 (2) Å, forming a three-dimensional network.
منابع مشابه
3a,11b-Dihydroxy-2-oxo-2,3,3a,11b-tetrahydro-1H-imidazo[4,5-f][1,10]phenanthrolin-7-ium chloride
In the crystal structure of the title compound, C(13)H(11)N(4)O(3) (+)·Cl(-), the dihedral angle between the two pyridine rings is 9.72 (9) Å. Ions are linked via N-H⋯Cl, O-H⋯Cl and O-H⋯O hydrogen bonds, forming a three-dimensional framework.
متن کامل2-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol monohydrate
The asymmetric unit of the title compound, C(19)H(12)N(4)O·H(2)O, contains one organic molecule and one solvent water mol-ecule, which are connected by N-H⋯O and O-H⋯N hydrogen bonds. In addition, there is one intra-molecular O-H⋯N hydrogen bond. The organic mol-ecule is essentially planar (r.m.s. deviation for all non-H atoms = 0.028 Å).
متن کاملBis(μ-cyclohexane-1,4-dicarboxylato)bis{aqua[1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol]cadmium} monohydrate
The asymmetric unit of the title compound, [Cd(2)(C(8)H(10)O(4))(2)(C(23)H(14)N(4)O)(2)(H(2)O)(2)]·H(2)O, consists of one half of the dimeric complex, which lies about an inversion centre, and a half-occupancy solvent water mol-ecule on a general position. Each Cd(II) cation is six-coordinated by the two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol (L) ligand an...
متن کامل[1-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol-κ2 N 7,N 8]diiodidomercury(II)
In the title compound, [HgI(2)(C(23)H(14)N(4)O)], the Hg(II) atom is four-coordinated by two N atoms from one 1-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)naphthalen-2-ol ligand and by two I atoms in a distorted tetra-hedral environment. An intra-molecular O-H⋯N hydrogen bond stabilizes the mol-ecular conformation and an inter-molecular N-H⋯I inter-action stabilizes the crystal packing.
متن کامل3-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)benzonitrile methanol solvate
In the title compound, C(20)H(11)N(5)·CH(3)OH, the benzene ring is twisted by a small dihedral angle of 1.89 (11)° with respect to the imidazo[4,5-f][1,10]phenanthroline ring system. N-H⋯O and O-H⋯N hydrogen bonding is present in the crystal structure.
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